Štruktúra a reaktivita – riešené príklady a úlohy. 1. časť

E-book

Michal Jaščur - Michal Hnatič

This textbook covers the fundamentals of phenomenological thermodynamics to the extent typically taught in standard theoretical physics courses at the undergraduate level in the Physics degree program. A slightly reduced scope is also taught in all interdisciplinary study programs combined with physics. In recent years, the time allocation for individual courses has been slightly reduced, which is reflected in our selection and coverage of topics.

Our primary aim was to provide a sufficiently solid explanation of the key concepts and laws of thermodynamics necessary for mastering further theoretical physics courses at the master's level (e.g., Statistical Physics, Condensed Matter Physics, Quantum Theory of Solids, Quantum Theory of Magnetism, etc.). The book also presents the essential minimum knowledge required for the study of further applications of thermodynamics in biophysics, biology, chemistry, and engineering disciplines.

Understanding individual sections, as well as the text as a whole, requires a grasp of the basic concepts of thermodynamics at the level of a General Physics course and knowledge equivalent to a standard university mathematics course. Each topic is treated with the utmost emphasis on conceptual clarity and mathematical rigor.

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E-book

Miroslava Matiková Maľarová

The university textbook entitled: Host-guest and supramolecular chemistry provides basic information about this scientific field as well as the types of compounds that belong to it. It provides basic characteristics of non-bonded interactions as well as methods of characterization and classification for these compounds. It summarizes knowledge about various types of host-guest systems from the oldest such as Hofmann clathrates to inclusive compounds such as cyclodextrins and calixarenes. In addition to structural and synthetic information, which is supplemented with images, the textbook also addresses the possibilities of application or practical use of compounds. The conclusion of each chapter is supplemented with tasks for elaboration on a given topic.

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E-book

Karel Saksl

Solving crystal structures is the royal discipline of X-ray crystallography. Its primary task, with the exception of defects, is to describe the atomic structure of the motif that, by its repetition, fills the volume of the entire crystal or crystalline phase. This task is nowadays more or less routine for single-crystal X-ray diffraction, which can locate hundreds to thousands of non-hydrogen atoms in large unit cells. However, in real practice, we often have material available only in powder form instead of single crystals. Solving the atomic structure from its X-ray diffraction data is non-trivial, mainly because the three-dimensional diffraction space of a single crystal is reduced to one dimension by measuring a large number of randomly oriented microcrystals (crystallites). Therefore, the solution itself requires, in addition to proper measurement methodology, the selection of suitable tools, procedures, and strategies that, through optimization, will lead to the solution and refinement of the given crystalline phase. The current limit of this method is approximately 100 non-hydrogen atoms in the asymmetric part of the unit cell, which, however, is sufficient for most inorganic materials.

The goal of these educational texts is to provide students in the second and third levels of university studies with specific guidance on solving crystal structures from powder X-ray diffraction data. These scripts build upon my first monograph and require practical knowledge of its content. Similar to my previous monograph, I offer solved examples without a deep theoretical introduction, demonstrating procedures and strategies leading to the correct solution of crystalline phases using the freely available GSAS-II program. The examples are arranged from simpler to more complex, and the reader will find many useful pieces of information in the literature references as well as in the comments below the line. Part of these scripts are data intended for your individual practice of the described procedures. 

Karel Sakls

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E-book

Ivana Sotáková-Martin Vavra-Mária Ganajová

This textbook has been designed for the master students of chemistry teaching (combined) at the Faculty of Science, Pavol Jozef Šafárik University in Košice as a source of model school experiments in general and inorganic chemistry. It will be used for teaching the Special Practice of School Experiments I compulsory course. It consists of instructions for experiments related to the selected topics in general and inorganic chemistry as well as the didactic and technical aspects of their performance. Each experiment includes an explanation of the principle, specification of the tools and chemicals needed, working procedure, and the respective apparatus assembly scheme. At the end of each experiment, the observation and explanation necessary for the correct interpretation of the results of the chemical experiment performed are provided. To follow the requirements for the digital transformation of education, selected computer-aided experiments and visualiser projections have been included as well. The next part is focused on the work with the monitoring suitcase, which can be used for making simple field experiments related to environmental topics. The final part is dedicated to attractive experiments that complement the topics in inorganic chemistry and can be used to motivate students. All experiment instructions are in line with the requirements specified by the state educational programmes for primary and grammar schools. This book allows teachers to select appropriate demonstrative experiments or experiments for laboratory classes performed by students themselves. The videos of selected experiments are also available as part of the interactive periodical table of elements operated by the Institute of Chemistry, Faculty of Science, Pavol Jozef Šafárik University in Košice.

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