Vybrané heterocyklické zlúčeniny

E-book

Karel Saksl

Solving crystal structures is the royal discipline of X-ray crystallography. Its primary task, with the exception of defects, is to describe the atomic structure of the motif that, by its repetition, fills the volume of the entire crystal or crystalline phase. This task is nowadays more or less routine for single-crystal X-ray diffraction, which can locate hundreds to thousands of non-hydrogen atoms in large unit cells. However, in real practice, we often have material available only in powder form instead of single crystals. Solving the atomic structure from its X-ray diffraction data is non-trivial, mainly because the three-dimensional diffraction space of a single crystal is reduced to one dimension by measuring a large number of randomly oriented microcrystals (crystallites). Therefore, the solution itself requires, in addition to proper measurement methodology, the selection of suitable tools, procedures, and strategies that, through optimization, will lead to the solution and refinement of the given crystalline phase. The current limit of this method is approximately 100 non-hydrogen atoms in the asymmetric part of the unit cell, which, however, is sufficient for most inorganic materials.

The goal of these educational texts is to provide students in the second and third levels of university studies with specific guidance on solving crystal structures from powder X-ray diffraction data. These scripts build upon my first monograph and require practical knowledge of its content. Similar to my previous monograph, I offer solved examples without a deep theoretical introduction, demonstrating procedures and strategies leading to the correct solution of crystalline phases using the freely available GSAS-II program. The examples are arranged from simpler to more complex, and the reader will find many useful pieces of information in the literature references as well as in the comments below the line. Part of these scripts are data intended for your individual practice of the described procedures. 

Karel Sakls

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Zuzana Orságová Králová (ed.)

The scientific book of abstracts is a summary of the contributions of teachers, scientists and other conference participants, which contain the original results of their scientific and research activities. Their work will be the subject of the next domestic conference "New trends in chemistry, research and education 2019". The conference is a space for dialogue between scientific academics on the one hand and professional staff and students on the other.

The contributions published in this volume can be divided according to content into the field of analytical, inorganic, physical, organic chemistry, biochemistry and didactics of chemistry. All contributions are interesting and can be used in further creative scientific and research work, in the process of education and in practical work.

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Marián Kireš - Renáta Orosová a kol.

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Katarína Cechlárová - Eva Pitoňáková (eds.)

Proceedings of Abstracts from Contributions by Participants of the Student Scientific Conference at the Faculty of Science, UPJŠ in Košice, Held on April 26, 2017

This is the fifth edition of the proceedings from the Student Scientific Conference (ŠVK) at the Faculty of Science, Pavol Jozef Šafárik University in Košice. We are pleased that ŠVK has become an integral part of faculty life and a showcase for the quality of education provided. In 2017, ŠVK took place as part of the traditional Science Days on April 26, 2017. 105 students from the Faculty of Science presented their work. Contributions were organized into 15 sections, supplemented by an open programming competition involving 17 students and the final round of the IHRA competition, which included 27 teams from across Slovakia.

The abstracts in this proceedings demonstrate that students at the Faculty of Science, UPJŠ, acquire knowledge and skills in their field not only through theoretical study of disciplines but also through active engagement in solving partial scientific problems aligned with research goals at the faculty’s institutes. These abstracts also provide an overview of the faculty’s scientific activity, which we believe will be of interest to the broader public.

doc. RNDr. Gabriel Semanišin, PhD.

Dean of the Faculty

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Karel Saksl

The aim of these study texts is to provide students in the second and third levels of higher education with specific guidance on processing 2D diffraction data, performing phase analysis from X-ray diffraction data, and refining microstructural parameters of identified phases using the Rietveld refinement method.

This guide is designed in the form of real-world tasks from materials research and leads the reader step by step through the processes of processing, evaluating, and interpreting the measured data. For this purpose, freely accessible programs such as Fit2D, QualX, POV-Ray, and GSAS II will be used, as well as a freely downloadable commercial program (Diamond) that allows for task execution in demonstration mode. Phase analysis will be conducted exclusively using the freely distributable crystallographic database Crystallography Open Database (COD).

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Erik Čižmár

Textbook Automation of Laboratory Experiments in LabVIEW environment is devoted to the basics of graphical programming and shows the way how to communicate with measuring equipment and Arduino development boards in LabVIEW. The basic concepts of creating a virtual instrument and its interactive user environment are introduced. Three physical tasks are presented, the practical implementation of which takes place with the use appropriate instrumentation and LabVIEW. Practical tasks are dedicated to measuring the transmission characteristics of a low-pass RC filter, measuring the natural resonant frequency of a quartz tuning fork using the heterodyne pulse method, and mapping the magnetic field of a permanent magnet using Arduino.

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Beáta Valkayed.
Ivana Slepáková-Lenka Maliničová a kol.

The EFFUSE Teacher's Guide is a practical educational material for primary and secondary school teachers who want to develop environmental awareness with their pupils through field-based learning. It is based on the concept of the EFFUSE project (‘Environment for the future by science education’), which aims to link science, research and education with environmental protection. The manual provides teachers with methodological support for planning and implementing outdoor activities aimed at observing and documenting organisms around the Laborec River and the Uh River. It contains instructions for working with real samples, basic biomonitoring procedures and offers the opportunity to participate in the creation of a virtual laboratory that mirrors the state of the local aquatic ecosystem. Through these activities, pupils will learn to understand the links between human activity and the state of the environment, while learning the basics of how scientists work in the fields of biology and ecology. The guide also motivates teachers to become agents of positive change, inspire the younger generation to be active and engage the community in conservation. It is a challenge and an opportunity to create a space for meaningful learning in line with current trends in environmental and digital education.

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Marcel Uhrin - Petr Benda -  Peter Kaňuch

Bats represent a unique group of mammals, characterised by different life strategies. They are the only mammals capable of active flight, which, combined with their almost exclusively nocturnal activity, has led to the evolution of specific adaptations. One of the most striking is echolocation, which enables them to orientate themselves perfectly in their surroundings in the dark. Bats are mainly native to the tropics, but have also colonised areas outside the tropics, which, has led to a complex phenological cycle with active phases and interruptions during hibernation, especially in temperate zones. In this diverse and species-rich group (almost 1,500 known species), there is a wide range of social organisation as well as feeding and roosting strategies. The textbook "Fundamentals of Chiropterology" brings the current state of knowledge about these extraordinary animals in eleven chapters and two appendices for the first time in the Slovak language.

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Jana Shepa (ed.)

The book of abstracts from the second year of the international conference Spring electrochemical meeting is composed of contributions from the participants of this student conference.

The conference consisted of one invited lecture and ten competing student lectures. The message of this meeting is to create a dialogue between students of electrochemistry and the mutual exchange of knowledge. All contributions are professionally processed and inspiring.

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Jozef Strečka

The present textbook deals with exactly solved models and their diverse applications in several branches of physics such as mathematical physics, statistical physics, condensed matter physics and so on. Exactly soluble models are currently considered as an inspiring research field in its own right, which regrettably requires a considerable knowledge of sophisticated mathematics. Accordingly, my primary ambition was to provide an intro- ductory course for undergraduate students that would cover the simplest exactly solved models, whose rigorous solutions are available even after modest calculation. The present textbook should be therefore regarded as an auxiliary graduate-level textbook, which should serve as the student’s guide on this beautiful but surely intricate subject.

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Mária Reháková 

Vysokoškolský učebný text určený pre poslucháčov vyšších ročníkov z bioanorganickej chémie. Štúdium bioanorganickej chémie si vyžaduje vedomosti z predchádzajúcich chemický disciplín nižších ročníkov - všeobecnej, anorganickej, organickej, fyzikálnej chémie a biochémie.

Autorka

E-book

Zuzana Kudličková(ed.)

Proceedings of Abstracts from the Scientific Conference with International Participation Organized on the Occasion of the 50th Anniversary of the Establishment of the Department of Organic Chemistry, Faculty of Science, Pavol Jozef Šafárik University in Košice, held on June 8–10, 2016 in Košice.

The Department of Organic Chemistry was established on February 1, 1966. From its inception, the department’s development prospects have been linked to high-quality scientific research focused on the synthesis of isothiocyanates and the products of their nucleophilic additions. In addition, studies were conducted on the use of cycloaddition, cyclocondensation, and photocyclization reactions of heterocumulenes in the synthesis of heterocycles.

Currently, research at the Department of Organic Chemistry is concentrated on stereoselective syntheses of iminosugars and γ-lactam-β-lactone antibiotics, total synthesis of natural compounds and their analogues possessing a sphingoid structure, research into the synthesis of indole alkaloids from the phytoalexin group, and the synthesis of acetylcholinesterase inhibitors based on acridine and coumarin derivatives.

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Monika Balogová - Viktória Vargová - Kristián Gulyás - Natália Pipová - Dalibor Uhrovič -Marcel Uhrin

A peer-reviewed publication dealing with the biology and ecology of the European green toad, bringing new findings through scientific research on the roosting ecology, spatial activity and dispersal of this protected species in urban environments. The subject matter of this publication is highly topical, as amphibians represent the most threatened vertebrate group in the world. This work is suitable not only for university students interested in batrachology, amphibian ecology, and vertebrate zoology, but also for conservation workers, municipalities, and specialists directly involved in the reconstruction of urban areas with green toads. Last but not least, this publication is suitable for enthusiasts with an interest in nature and its conservation.

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Jozef Bednarčík (ed.)

Pavol Jozef Šafárik University in Košice under the auspices of Ministry of Education, Research, Development and Youth of the Slovak Republic, Ministry of Economy of the Slovak Republic and European X-Ray Free-Electron Laser Facility GmbH in Hamburg organizes School of XFEL and Synchrotron Radiation Users 2024 (SFEL 2024). The school is continuation of the Winter Schools of Synchrotron radiation held in 2011, 2013, 2014 and SFEL 2017, 2018, 2019 and 2022. The aim of the SFEL2024 school is to facilitate the growth of new Slovak research community of high expertise in high-efficiency RTG laser and synchrotron and neutron sources. The SFEL school is designed for efficient transfer of the rapidly developing know-how in these areas to young generation – researchers and university students. The next aim of the SFEL2024 is strengthening of personal connections between the local Slovak research community and forming scientific teams of XFEL users. Slovak research community thus can take advantage of the fact that Slovakia is a shareholder of European XFEL GmbH Company in Hamburg, but also makes more efficient use of other closely related scientific facilities, including ILL and ESRF in Grenoble and DESY in Hamburg.

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Ľubomír Antoni-Stanislav Krajči

An important part of theoretical computer science is the problem of Turing machines. This computational model has two basic properties: like any other computational program, the software of a Turing machine is composed of instructions, but in its case they are all of a single type. Every other (so far known) computer program can be transformed into a Turing machine program without loss of information. While the second feature reduces the question of what a calculator cannot do to the question of what a Turing machine cannot do, the first feature allows a much simpler investigation of such a question. Using this computational model, we can thus find concrete problems that no automaton can ever deal with (perhaps the most famous is the problem of the Turing machine stopping). Their existence demonstrates the fundamental limitations of (not only ideal) computational means, and thus encourages both criticality and humility in our thinking.

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E-publication
Mária Vilková-Zuzana Kudličková-Ján Elečko
This study material is intended for students of chemistry and related disciplines interested in applied nuclear magnetic resonance (NMR) and physical chemistry. It offers practice-oriented tasks designed to develop skills in NMR spectroscopy, quantitative analysis, and data interpretation. Students learn modern approaches to determining physicochemical parameters (e.g., partition coefficients, pKa values, keto–enol equilibria, or enantiomeric excess) and gain experience with software tools for spectrum processing.
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