Vybrané kapitoly z elektrochémie
E-book
Kveta Markušová - Daniela Kladeková
Electrochemistry is the science that studies ionic systems and the processes or phenomena that occur at the interface between ionic systems and metals or semiconductors. At the current stage of development, electrochemistry can be divided into two main areas based on its focus. The first one - ionics - deals with the properties of ionic systems (solutions, melts, solid electrolytes). The second area - electrodeics - focuses on phenomena at the electrode/ionic system interface.
Both ionics and electrodeics investigate equilibrium and non-equilibrium phenomena and processes. Research into the properties of ionic systems under equilibrium conditions provides information and insights into the structure and composition of electrolyte solutions, melts, and solid electrolytes, while measurements under non-equilibrium conditions provide data on the electrical conductivity of ionic systems. In the field of electrodeics, the study of equilibria at the electrode/solution (or melt) interface is the domain of electrochemical thermodynamics. Measuring the rates of processes occurring at this phase interface and explaining the principles governing these processes fall under the scope of electrode process kinetics or electrochemical kinetics.