Praktické cvičenia z röntgenovej difraktometrie

E-book

Karel Saksl

The aim of these study texts is to provide students in the second and third levels of higher education with specific guidance on processing 2D diffraction data, performing phase analysis from X-ray diffraction data, and refining microstructural parameters of identified phases using the Rietveld refinement method.

This guide is designed in the form of real-world tasks from materials research and leads the reader step by step through the processes of processing, evaluating, and interpreting the measured data. For this purpose, freely accessible programs such as Fit2D, QualX, POV-Ray, and GSAS II will be used, as well as a freely downloadable commercial program (Diamond) that allows for task execution in demonstration mode. Phase analysis will be conducted exclusively using the freely distributable crystallographic database Crystallography Open Database (COD).

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Quantity

978-80-8152-874-3

Data sheet

Method of publication:
E-book (pdf)
Author:
Karel Saksl
Document type:
Course Notes
Number of pages:
73
Available from:
07.07.2020
Year of publication:
2020
Edition:
1st edition
Publication language:
Slovak
Faculty:
Prírodovedecká fakulta
- Free for download

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Bibliography of the amphibian and reptile research in Slovakia between 1791 and 2017

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Authors

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Veríme, že predložené informácie v tejto publikácii môžu prispieť k ochrane nielen populácií ropúch zelených v meste Košice, ale

Ropucha zelená v meste Košice

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Monika Balogová - Viktória Vargová - Kristián Gulyás - Natália Pipová - Dalibor Uhrovič -Marcel Uhrin

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Praktické cvičenia z röntgenovej difraktometrie II

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E-book

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Karel Saksl

Solving crystal structures is the royal discipline of X-ray crystallography. Its primary task, with the exception of defects, is to describe the atomic structure of the motif that, by its repetition, fills the volume of the entire crystal or crystalline phase. This task is nowadays more or less routine for single-crystal X-ray diffraction, which can locate hundreds to thousands of non-hydrogen atoms in large unit cells. However, in real practice, we often have material available only in powder form instead of single crystals. Solving the atomic structure from its X-ray diffraction data is non-trivial, mainly because the three-dimensional diffraction space of a single crystal is reduced to one dimension by measuring a large number of randomly oriented microcrystals (crystallites). Therefore, the solution itself requires, in addition to proper measurement methodology, the selection of suitable tools, procedures, and strategies that, through optimization, will lead to the solution and refinement of the given crystalline phase. The current limit of this method is approximately 100 non-hydrogen atoms in the asymmetric part of the unit cell, which, however, is sufficient for most inorganic materials.

The goal of these educational texts is to provide students in the second and third levels of university studies with specific guidance on solving crystal structures from powder X-ray diffraction data. These scripts build upon my first monograph and require practical knowledge of its content. Similar to my previous monograph, I offer solved examples without a deep theoretical introduction, demonstrating procedures and strategies leading to the correct solution of crystalline phases using the freely available GSAS-II program. The examples are arranged from simpler to more complex, and the reader will find many useful pieces of information in the literature references as well as in the comments below the line. Part of these scripts are data intended for your individual practice of the described procedures. 

Karel Sakls

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ATÓMOVÁ ŠTRUKTÚRA LÁTOK I - Základy RTG kryštalografie

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Crystallography deals with discerning the arrangement and bonding of atoms in crystalline solids. Almost immediately after their discovery, X-rays began to be used to study the internal structure of substances.

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Next, energy levels and allowed transitions within an atom with multiple electrons are described. The second chapter concludes with the characterization of the basic absorption and emission processes. The third chapter is devoted to the production of X-ray radiation and its properties. Sources of X-ray radiation and a description of their operation are presented.

Interaction of X-ray radiation with matter, absorption and detection of X-ray radiation are the subject of the last part of this chapter.

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